
Chemistry Letters p. 1889 - 1892 (1994)
Update date:2022-08-05
Topics:
Yamago, Shigeru
Ejiri, Satoshi
Nakamura, Eiichi
Hydrostannation of substituted cyclopropenone acetals with trialkyltin hydride takes place smoothly under radical conditions to afford a variety of 2-alkyl-3-stannylcyclopropanone acetals in high yield.Comparison of the cyclopropene with acetylenes with the aid of inter- and intramolecular competitive experiments revealed the kinetically controlled nature of the reaction of the cyclopropene reaction.
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(1994)