
Tetrahedron Letters p. 7387 - 7390 (1994)
Update date:2022-08-05
Topics:
Bienayme, Hugues
Palladium-catalysed transformation of readily available mixed carbonates 1a-l gives rise to a variety of allenic polyunsaturated aldehydes and ketones 2a-l. These carbonyls were sometimes contaminated with minor amounts of the undesired acetylenic regioisomers 3, and could be purified by silicagel chromatography.
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(1994)