Chemical Communications p. 2607 - 2608 (1996)
Update date:2022-08-03
Topics:
Peng, Wei-Jun
Train, Spencer G.
Howell, Donna K.
Fronczek, Frank R.
Stanley, George G.
The X-ray structure of an unsymmetrical tetraphosphine bridged zwitterionic Rh-IRhI dinuclear tetracarbonyl complex is reported along with the facile CO addition equilibrium to form an Rh0 tetraphosphine pentacarbonyl bimetallic species; both of these are poor hydroformylation catalysts due to the relatively high electron density on the rhodium centres, in marked contrast to a dicationic bimetallic RhII complex based on the same tetraphosphine ligand that is a highly active and regioselective hydroformylation catalyst.
Contact:+86-10-62651721
Address:29 Yongxing Road, Daxing District,Beijing China
Feis International Trade Co,. Ltd
Contact:13961823444-18235944442
Address:Wuxi jiangsu
FUJIAN SHANSHUI CHEMICAL CORP.LTD.
Contact:+86-151-59920036
Address:Jinqiao Gareden, jo@fj-xinyi.com
Lanzhou huibang biological chemical technology Co., LTD
Contact:0931-7843964
Address:NO.2011,Yannan Road,Chengguan,
Contact:+852 83038667
Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
Doi:10.1016/S0040-4039(00)76897-3
(1994)Doi:10.1016/j.cclet.2014.01.019
(2014)Doi:10.1016/S0040-4039(00)00970-9
(2000)Doi:10.1016/S0040-4039(01)93809-2
(1989)Doi:10.1016/S0022-1139(00)84379-1
(1989)Doi:10.1080/00958972.2011.556721
(2011)
