Russian Chemical Bulletin p. 492 - 499 (1995)
Update date:2022-09-26
Topics:
Grigorieva, N. Ya.
Pinsker, O. A.
Buevich, A. V.
Moiseenkov, A. M.
A highly-stereoselective method (90percent of the Z-isomer) was developed for the Peterson olefination of ketones with nerylacetone (1) as an example.The method is based on the introduction of a PhS group, which is removed after completion of the reaction, at the ketone C(3) atom. - Keywords: olefination of ketones, stereoselective synthesis, Peterson reaction, 2Z- and 2E-4-phenylthiofarnesoles and 2Z- and 2E-4-phenylthiofarnesoates
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