Tetrahedron Letters p. 8731 - 8734 (1994)
Update date:2022-07-29
Topics:
Corey
Chen, Zhuoliang
The racemic α-silyl organolithium reagents 2a and 2b react with (R)-styrene oxide enantioselectively to produce the chiral γ-hydroxysilanes 3a and 3b, respectively. The chiral 1,3-diol 4 and cyclopropane 7 are readily obtained in enantiomerically pure form from these γ-hydroxysilanes.
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(2014)
