An Enantiospecific Entry to Fluoro Substituted Aminocyclopentanols through Intramolecular Nitrile Oxide, Nitrone, and Oxime Cycloaddition Reactions

DOI: 10.1016/0957-4166(94)80052-9

Source and publish data:

Tetrahedron Asymmetry p. 1019 - 1028 (1994)

Update date:2022-07-30

Topics: Enantiomer Nitrile oxide Oxime Intramolecular Cycloaddition Enantiospecific Nitrone

Authors:

Arnone, Alberto

Cavicchioli, Marcello

Donadelli, Alessandro

Resnati, Giuseppe

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Article abstract of DOI:10.1016/0957-4166(94)80052-9

Starting from (2R,3S)-2-benzyloxy-3-fluoro-5-hexenale 2 and its (2R,3R) epimer, cyclopentanoisoxazolidines 4 and 7 are obtained with complete diastereoselectivity through nitrone and oxime intramolecular cycloaddition reactions.In contrast, cyclopentanois

Full text of DOI:10.1016/0957-4166(94)80052-9

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