An Enantiospecific Entry to Fluoro Substituted Aminocyclopentanols through Intramolecular Nitrile Oxide, Nitrone, and Oxime Cycloaddition Reactions

DOI: 10.1016/0957-4166(94)80052-9

Source and publish data:

Tetrahedron Asymmetry p. 1019 - 1028 (1994)

Update date:2022-07-30

Topics: Enantiomer Nitrile oxide Oxime Intramolecular Cycloaddition Enantiospecific Nitrone

Authors:

Arnone, Alberto

Cavicchioli, Marcello

Donadelli, Alessandro

Resnati, Giuseppe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(94)80052-9

Starting from (2R,3S)-2-benzyloxy-3-fluoro-5-hexenale 2 and its (2R,3R) epimer, cyclopentanoisoxazolidines 4 and 7 are obtained with complete diastereoselectivity through nitrone and oxime intramolecular cycloaddition reactions.In contrast, cyclopentanois

Full text of DOI:10.1016/0957-4166(94)80052-9

Products guided by the article

Product name:(3R,4R,5aR)-3-benzyloxy-4-fluorocyclopentano2-isoxazoline

Cas No:160332-05-8

R&D Labs maybe for 160332-05-8

Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
shanghai tuomiao chemicial co.,ltd.

website:https://www.tuomiaochem.com/

Contact:021 - 59853336

Address:shanghai
Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china

Relevant to this article

Potassium tert -Butoxide Mediated Arylation of 2-Substituted Malononitriles Using Diaryliodonium Salts

Doi:10.1055/s-0036-1589061
(2017)
Synthesis of gem-difluoromethylene building blocks through regioselective allylation of gem-difluorocyclopropanes

Doi:10.1021/ol500803r
(2014)
Highly enantioselective Michael addition of diethyl malonate to chalcones catalyzed by cinchona alkaloids-derivatived bifunctional tertiary amine-thioureas bearing multiple hydrogen-bonding donors

Doi:10.1039/c4ob00203b
(2014)
Aldol equilibrations of unprotected trihydroxybicyclic lactones: Enantiomeric Tetrahydroxy-α-aminocyclopentane carboxylic acids from epimeric bicyclic lactones

Doi:10.1016/S0040-4039(00)78528-5
(1994)
Metal-Oxidant-Free Cobalt-Catalyzed C(sp²)-H Carbonylation of ortho-Arylanilines: An Approach toward Free (NH)-Phenanthridinones

Doi:10.1021/acs.joc.8b00730
(2018)
Unpredictable reaction of phenyltrichlorosilane with tert-butyllithium

Doi:10.1016/j.inoche.2014.02.039
(2014)

Article Doi