Tetrahedron p. 10539 - 10548 (1994)
Update date:2022-08-05
Topics:
Ferraboschi, Patrizia
Grisenti, Paride
Manzocchi, Ada
Santaniello, Enzo
The results from the baker's yeast-mediated reduction of the acetates 3a- d and the methyl ethers 5a-d were compared with the same biotransformation which converts the α-hydroxy ketones 1a-d into the (R)-diols 2a-d (90- 98%ee); the acetates 3a-d afford the (S)-monoacetates 4a-d (72-94% ee) and the methyl ethers 5a-d are reduced to the (R)-monoethers 6a-d (64-76% ee).
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