A Luminescent Heterometallic Au(I)...Cu(I) Complex. Spectroscopic Properties and Crystal Structures of and 2> (C7H5N2 = 7-azaindolate)

DOI: 10.1039/DT9940003677

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3677 - 3682 (1994)

Update date:2022-08-03

Topics:

Authors:

Chan, Chi-Keung

Guo, Chun-Xiao

Cheung, Kung-Kai

Li, Dan Li, Dan

Che, Chi-Ming

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940003677

The mono- and tetra-nuclear complexes 1 and <2> 2, the latter containing 7-azaindolate (C7H5N2(1-)) bridging ligands, have been prepared and their crystal structures determined.The intramolecular Au...Cu and Cu...Cu separations in 2 are 3.0104(6) and 2.941(1) Angstroem respectively.Extended-Hueckel molecular-orbital calculations revealed a weak Au(I)...Cu(I) bonding interaction but no Cu(I)...Cu(I) interaction.In acetonitrile, both complexes display intense intraligand emission at 510 nm upon photoexcitation with UV/VIS light at room temperature.In the solid state 2 shows an emission at 550 nm.

Full text of DOI:10.1039/DT9940003677

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Au(PPh3)(μ-7-azaindolate)Cu(μ-7-azaindolate)]2

Cas No:160602-74-4

R&D Labs maybe for 160602-74-4

Nanjing Yuance Industry&Trade Co., Ltd.

website:http://www.njyuance.cn/

Contact:+86-25-85439097

Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
Nantong Auxin Electronic Technology Co., LTD

Contact:86-513-88760026

Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Tianjin Tongde Biological Technology Co., Ltd.

Contact:86-22-23309138

Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
Landz International Company Ltd.

Contact:0086-21-58891610

Address:985 Dongfang Road, Pudong, Shanghai 200122 China

Relevant to this article

Synthesis of a Series of Enantiopure Polyhydroxylated Bicyclic N-Heterocycles from an L -Erythrose-Derived Nitrone and Alkoxyallenes

Doi:10.1002/ejoc.201301406
(2014)
Synthesis and characterization of new alkoxide and aryloxide derivatives of titanium and zirconium. X-ray molecular structure of

Doi:10.1016/0022-328X(94)05004-U
(1995)
Exclusive ring opening of gem-dihalo-1,2-cyclopropanated oxyglycal to oxepines in AgOAc

Doi:10.1016/j.carres.2014.01.023
(2014)
Synthesis and application of phenyl Nitrone derivatives as acidic and microbial corrosion inhibitors

Doi:10.1155/2015/201259
(2015)
A highly sensitive and reductant-resistant fluorescent probe for nitroxyl in aqueous solution and serum

Doi:10.1039/c4cc01440e
(2014)
Ring-opening polymerization of rac-lactide with aluminum chiral anilido-oxazolinate complexes

Doi:10.1021/om401226j
(2014)

Article Doi