Stereoselective construction and synthetic applications of phenylthio substituted iodoolefins

Article abstract of DOI:10.1016/0040-4039(90)80120-B

(E)- and (Z)-Phenylthio substituted iodoolefins 1 and 2 have been synthesized stereoselectively via lower order stannylcuprate addition to and hydroalumination of appropriate alkyne precursors. Their utility in model studies on the synthesis of calichemic