Synthesis of (E)-Olefin Dipeptide Isosteres

DOI: 10.1016/0040-4039(94)88055-7

Source and publish data:

Tetrahedron Letters p. 5985 - 5988 (1994)

Update date:2022-07-29

Topics:

Authors:

McKinney, Judi A.

Eppley, Daniel F.

Keenan, Richard M.

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Article abstract of DOI:10.1016/0040-4039(94)88055-7

A route to the synthesis of (E)-olefin dipeptide isosteres is reported.The key step involves an orthoester Claisen rearrangement of an allylic alcohol derived from commercially available amino acids.Chirality transfer from the alcohol center to the newly

Full text of DOI:10.1016/0040-4039(94)88055-7

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