The synthesis of A-nor-B-homobaccatin III derivatives

DOI: 10.1016/S0040-4039(00)78269-4

Source and publish data:

Tetrahedron Letters p. 6547 - 6550 (1994)

Update date:2022-08-02

Topics:

Authors:

Appendino, Giovanni

Jakupovic, Jasmin

Cravotto, Giancarlo

Varese, Marcella

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Article abstract of DOI:10.1016/S0040-4039(00)78269-4

Treatment with activated MnO₂ of 7-protected derivatives of 10- deacetylbaccatin III and 14β-hydroxy-10-deacetylbaccatin III gave A-nor-B- homotaxoids resulting from α-ketol rearrangement of 13,14-dioxotaxane intermediates.

Full text of DOI:10.1016/S0040-4039(00)78269-4

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