The Geometry of the Carbanionic Moiety Influences the Non-Induced Diastereoselectivity of the -Wittig Rearrangement of Lithiated Diallyl Ethers

DOI: 10.1016/S0040-4020(01)90391-6

Source and publish data:

Tetrahedron p. 3687 - 3708 (1994)

Update date:2022-08-02

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Authors:

Goeppel, Dirk

Muenster, Ingo

Brueckner, Reinhard

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Article abstract of DOI:10.1016/S0040-4020(01)90391-6

Lithiated diallyl ethers with cis- or trans-configuration of the anionic moiety were generated from the diallyl ethers 10, from the vinylogous O,S-acetals 13, and from the O,S-acetals 14 by treatment with nBuLi (in the case of 10) or with lithium naphthal

Full text of DOI:10.1016/S0040-4020(01)90391-6

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