Nucleophilic aromatic substitution reactions of 1-methoxy-2- (diphenylphosphinyl)naphthalene with C-, N-, and O-nucleophiles: Facile synthesis of diphenyl(1-substituted-2-naphthyl)phosphines

DOI: 10.1055/s-1994-25438

Source and publish data:

Synthesis p. 199 - 202 (1994)

Update date:2022-07-30

Topics:

Authors:

Hattori Hattori

Sakamoto

Hayashizaka

Miyano Miyano

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Article abstract of DOI:10.1055/s-1994-25438

A novel nucleophilic aromatic substitution reaction is described in which the methoxy group of 1-methoxy-2-(diphenylphosphinyl)-naphthalene is readily replaced with Grignard reagents, alkoxides, and amides. Reduction of the resulting phosphine oxides provides a convenient route to diphenyl(1- substituted-2-naphthyl)phosphines.

Full text of DOI:10.1055/s-1994-25438

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