The Chemistry of Vicinal Tricarbonyls. A New Synthesis of Substituted Furans.

DOI: 10.1016/0040-4039(94)88385-8

Source and publish data:

Tetrahedron Letters p. 9783 - 9786 (1994)

Update date:2022-07-29

Topics:

Authors:

Wasserman, Harry H.

Lee, Gary M.

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Article abstract of DOI:10.1016/0040-4039(94)88385-8

Enolates of acyl phosphoranylidene carboxylates react with aldehydes to form secondary alcohols which undergo intramolecular addition to the central carbonyl of a vicinal tricarbonyl unit, generated in a separate step.The resulting dihydrofuranols undergo acid-catalyzed dehydration to form 3-hydroxyfuran-2-carboxylates.

Full text of DOI:10.1016/0040-4039(94)88385-8

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