Heterobinuclear hydrido, alkyl, and related complexes of Rh/Os. Site-specific reductive elimination of methane from a Rh/Os core and the structures of [RhOs(CH2CN)(CO)3(dppm)2] and [RhOs(CH3)(CO)3(dpp

DOI: 10.1021/ja00106a028

Source and publish data:

Journal of the American Chemical Society p. 245 - 258 (1995)

Update date:2022-07-30

Topics:

Authors:

Sterenberg, Brian T.

Hilts, Robert W.

Moro, Giovanni

McDonald, Robert

Cowie, Martin

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Article abstract of DOI:10.1021/ja00106a028

This paper reports the synthesis and characterization of a series of hydrido, alkyl, alkenyl, and related heterobimetallic complexes of Rh and Os and the site-specific reductive elimination of methane from hydrido methyl complexes. Reaction of [RhOs(CO) View More

Full text of DOI:10.1021/ja00106a028

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Product name:[RhOs(CO)4((C₆H₅)2PCH₂P(C₆H₅)2)((C₆H₅)2PCH(CH₃)P(C₆H₅)2)]⁽¹⁺⁾*(CF₃SO₃)^(1-)=[RhOs(CO)4(C₆H₅)8P₄C₃H₆](CF₃SO₃)

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