Heterobinuclear hydrido, alkyl, and related complexes of Rh/Os. Site-specific reductive elimination of methane from a Rh/Os core and the structures of [RhOs(CH2CN)(CO)3(dppm)2] and [RhOs(CH3)(CO)3(dpp

Article abstract of DOI:10.1021/ja00106a028

This paper reports the synthesis and characterization of a series of hydrido, alkyl, alkenyl, and related heterobimetallic complexes of Rh and Os and the site-specific reductive elimination of methane from hydrido methyl complexes. Reaction of [RhOs(CO)