Stereoselectivity of Addition of Organometallic Reagents to Pentodialdo-1,4-furanoses: Synthesis of L-Axenose and D-Evermicose from a Common Intermediate

DOI: 10.1021/jo00106a035

Source and publish data:

Journal of Organic Chemistry p. 202 - 211 (1995)

Update date:2022-07-30

Topics: Synthesis Addition Organometallic reagents Stereoselectivity Common intermediate

Authors:

Giuliano, Robert M.

Villani, Frank J.

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Article abstract of DOI:10.1021/jo00106a035

The additions of organometallic reagents to two pentodialdo-1,4-furanosides (methyl 3-O-benzyl-2-deoxy-α-D-erythro-pentofuranoside and its β-anomer) were carried out under a variety of experimental conditions.Methylmagnesium halides, methyllithium, methyl

Full text of DOI:10.1021/jo00106a035

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Product name:Methyl 3-O-benzyl-2-deoxy-5-α-D-erythro-pentodialdo-1,4-furanoside

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