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Highly Regio- and Stereo-specific Preparation of a New Carbohydrate-based 1,3-Oxazin-2-one by the INIR Method and its Applications in Some Asymmetric Transformations

DOI: 10.1016/S0957-4166(00)80392-4

Source and publish data:

Tetrahedron Asymmetry p. 2447 - 2458 (1994)

Update date:2022-07-29

Topics:

Authors:

Banks, Malcolm R.Banks, Malcolm R.

Cadogan, J. I. G.Cadogan, J. I. G.

Gosney, IanGosney, Ian

Gaur, SuneelGaur, Suneel

Hodgson, Philip K. G.Hodgson, Philip K. G.

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Article abstract of DOI:10.1016/S0957-4166(00)80392-4

Preliminary experiments show that a new gulonic acid-derived 1,3-oxazin-2-one, prepared by an intramolecular nitrene insertion reaction (INIR) method, serves to control both asymmetric aldol and Diels-Alder reactions with excellent stereo-selection.

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Full text of DOI:10.1016/S0957-4166(00)80392-4

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Product name:(5S,9S)-4-aza-5,9:6,10-di-O-isopropylidene-2,8-dioxabicyclo<4.3.0>nonan-3-one

Cas No:161687-24-7

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