Highly Regio- and Stereo-specific Preparation of a New Carbohydrate-based 1,3-Oxazin-2-one by the INIR Method and its Applications in Some Asymmetric Transformations

DOI: 10.1016/S0957-4166(00)80392-4

Source and publish data:

Tetrahedron Asymmetry p. 2447 - 2458 (1994)

Update date:2022-07-29

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Authors:

Banks, Malcolm R.

Cadogan, J. I. G.

Gosney, Ian

Gaur, Suneel

Hodgson, Philip K. G.

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Article abstract of DOI:10.1016/S0957-4166(00)80392-4

Preliminary experiments show that a new gulonic acid-derived 1,3-oxazin-2-one, prepared by an intramolecular nitrene insertion reaction (INIR) method, serves to control both asymmetric aldol and Diels-Alder reactions with excellent stereo-selection.

Full text of DOI:10.1016/S0957-4166(00)80392-4

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