Epimerisation-free Peptide Formation from Carboxylic Acid Anhydrides and Azido Derivatives

DOI: 10.1039/c39950000091

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 91 - 92 (1995)

Update date:2022-08-03

Topics: Yield Purification Reaction Conditions

Authors:

Bosch, Imma

Urpi, Felix

Vilarrasa, Jaume

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Article abstract of DOI:10.1039/c39950000091

Conversion of C-terminal carboxy groups of N-protected α-amino acids to the corresponding 3,5-dinitrobenzoyl mixed anhydrides, followed by treatment with α-azido esters and trialkylphosphines, affords good yields of peptides, without appreciable formation

Full text of DOI:10.1039/c39950000091

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