Terdentate (P,N,N) Complexes of a New Pyridyl Azine Phosphine Z,E-PPh2CH2(t-Bu)C=N-N=C(Me)C5H4N and its Deprotonated Derivative (an Azo Phosphine) with Transition Metals

DOI: 10.1039/DT9950000625

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 625 - 632 (1995)

Update date:2022-08-05

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Authors:

Hii, King Kuok

Perera, Sarath D.

Shaw, Bernard L.

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Article abstract of DOI:10.1039/DT9950000625

tert-Butyl diphenylphosphinomethyl ketone hydrazone, Z-PPh2CH2C(t-Bu)=NNH2 condensed with 2-acetylpyridine to give Z,E-PPh2CH2(t-Bu)C=N-N=C(Me)C5H4N Ia, which reacts with (nbd = norbornadiene) to give highly coloured tricarbonyl complexes View More

Full text of DOI:10.1039/DT9950000625

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Product name:[PdCl(PPh₂CH₂(t-Bu)C=NN=C(Me)C₅H₄N)]PF₆

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