Tandem carbonyl ene cyclization-cycloalkylation: A route to trifluoromethyl diterpenoids

DOI: 10.1016/S0040-4020(01)89305-4

Source and publish data:

Tetrahedron p. 11921 - 11932 (1994)

Update date:2022-08-03

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Authors:

Abouabdellah, Ahmed

Bonnet-Delpon, Daniele

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Article abstract of DOI:10.1016/S0040-4020(01)89305-4

A new sequential carbonyl-ene cyclization/cycloalkylation of trifluoromethyl ketones catalyzed by aluminum Lewis acids is described. From ketone 1, the 4-CF₃-4-OH cis-octahydrophenanthrene 6 is obtained in 50% yield. From ketone 2, with MeAlCl<

Full text of DOI:10.1016/S0040-4020(01)89305-4

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