Tetrahedron p. 11921 - 11932 (1994)
Update date:2022-08-03
Topics:
Abouabdellah, Ahmed
Bonnet-Delpon, Daniele
A new sequential carbonyl-ene cyclization/cycloalkylation of trifluoromethyl ketones catalyzed by aluminum Lewis acids is described. From ketone 1, the 4-CF3-4-OH cis-octahydrophenanthrene 6 is obtained in 50% yield. From ketone 2, with MeAlCl<
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