Hetero Diels-Alder reaction involving (E)-3-(tert-butyldimethylsiloxy)-1-(2',3',4',6'-tetra-O-acetyl -β-D-gl ucopyranosyloxy)buta-1,3-diene and p-nitrobenzaldehyde

DOI: 10.1016/S0040-4039(00)73430-7

Source and publish data:

Tetrahedron Letters p. 6351 - 6354 (1994)

Update date:2022-08-05

Topics:

Authors:

Lowe Lowe

Stoodley

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Article abstract of DOI:10.1016/S0040-4039(00)73430-7

The title reaction, when carried out in carbon tetrachloride in the presence of a catalytic amount of Eu(fod)₃, leads mainly to the cis-cycloadduct 6a; the product undergoes isomerisation to its epimer 7a in the presence of the catalyst in dich

Full text of DOI:10.1016/S0040-4039(00)73430-7

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Product name:Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-[(2R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-(4-nitro-phenyl)-5,6-dihydro-2H-pyran-2-yloxy]-tetrahydro-pyran-4-yl ester

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