Synthesis and Characterisation of Precursors to Organometal Networks

DOI: 10.1039/DT9950000843

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 843 - 850 (1995)

Update date:2022-08-03

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Authors:

Blake, Alexander J.

Johnson, Brian F. G.

Reed, David

Shephard, Douglas S.

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Article abstract of DOI:10.1039/DT9950000843

Thermolysis of triruthenium dodecacarbonyl in the presence of the appropriate dicyclic ligand C6H5(CH2)nPh in octane afforded organometallic clusters with the general formula 6-C6H5(CH2)nPh>>.The molecular structures of the three octahedral cluster compounds (n = 0 1, 1 2 or 2 3) have been established by single-crystal X-ray analysis.In all three the ligand occupies an apical position formally replacing three carbonyl units on a single metal site of .Studies of the 1H NMR spectra of compounds 1-3 have revealed a trend in electronic inductive effects.Thermolysis of in the presence of an excess of trans-stilbene afforded 3 and trans-<η⁶-C6H5(CH2)2Ph>> 4 in good yield.

Full text of DOI:10.1039/DT9950000843

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