
Chemistry of Heterocyclic Compounds p. 218 - 221 (1994)
Update date:2022-08-03
Topics:
Kelarev, V. I.
Koshelev, V. N.
Belov, N. V.
Malova, O. V.
Karakhanov, R. A.
6-Substituted 2,4-bis(trichloromethyl)-sym-triazenes containing the 2,6-di-tert-butylphenol group are synthesized by simultaneous cyclotrimerization of trichloroacetonitrile with the nitrile or thiocyanate derivative of the sterically hindered phenol in the presence of gaseous HCl.Significant amounts of 2,4,6-tris(trichloromethyl)-sym-triazene are formed as a by-product.
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