
Journal of the Chemical Society. Chemical communications p. 764 - 765 (1983)
Update date:2022-08-03
Topics:
Regan, Andrew C.
Staunton, James
An ortho-toluate carbanion generated from (2) by the chiral lithium amide base (6), (7), or (11) undergoes an enantioselective aldol-type reaction with acetaldehyde to give mellein methyl ether (3), in up to 53 percent enantiomeric excess.
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