Asymmetric Synthesis of Mellein Methyl Ether: Use of ortho-Toluate Carbanions Generated by Chiral Bases

DOI: 10.1039/c39830000764

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 764 - 765 (1983)

Update date:2022-08-03

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Authors:

Regan, Andrew C.

Staunton, James

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Article abstract of DOI:10.1039/c39830000764

An ortho-toluate carbanion generated from (2) by the chiral lithium amide base (6), (7), or (11) undergoes an enantioselective aldol-type reaction with acetaldehyde to give mellein methyl ether (3), in up to 53 percent enantiomeric excess.

Full text of DOI:10.1039/c39830000764

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