Enantioselective Synthesis of γ- and δ-Lactones

DOI: 10.1016/0957-4166(94)80107-X

Source and publish data:

Tetrahedron Asymmetry p. 1443 - 1446 (1994)

Update date:2022-08-03

Topics: Synthesis Diastereoselectivity Enantioselective Stereochemistry Nucleophilic addition Asymmetric catalysis Organocatalysis Chirality Oxidative Coupling Transition Metal Complexes

Authors:

Ruano, Jose L. Garcia

Fuerte, Araceli

Maestro, M. Carmen

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Article abstract of DOI:10.1016/0957-4166(94)80107-X

The synthesis of enantiomerically pure sulfinyl oxoacids HO2CCH2(CH2)_nCOCH(R)SOTol (n = 1 and 2, R = H, CH3), and their stereoselective reduction with DIBAL catalysed by ZnBr2 are reported.The resulting hydroxysulfoxides were cyclized in situ u

Full text of DOI:10.1016/0957-4166(94)80107-X

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Product name:(R)-4-Hydroxy-5-((R)-toluene-4-sulfinyl)-pentanoic acid

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