Oxidative addition of RCOI to [AsPh4][Rh(CO)2I2]. Synthesis of [AsPh4][RCORh(CO)2I3] (R=Me, Et, n-Pr, i-Pr)

DOI: 10.1016/0277-5387(94)00386-S

Source and publish data:

Polyhedron p. 167 - 174 (1995)

Update date:2022-08-03

Topics:

Authors:

Howe, Laurie A.

Bunel, Emilio E.

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Article abstract of DOI:10.1016/0277-5387(94)00386-S

Reaction of [AsPh4][Rh(CO)2I2] (1) with RCOI yields complexes [AsPh4]2[RCORh(CO)I3]2 (2, R=Me; 3, R=Et; 4, R=n-Pr; 5, R=i-Pr). The (13)CO scrambling process for complexes [AsPh4][RCORh((13)CO)(S)I3] (R=Me, Et; S=CD3CN) along with the skeleton isomerizatio

Full text of DOI:10.1016/0277-5387(94)00386-S

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Product name:Rh(CH₃⁽¹³⁾CO)(CO)(CD₃CN)I₃^(1-)*As(C₆H₅)4⁽¹⁺⁾=[As(C₆H₅)4][Rh(CH₃⁽¹³⁾CO)(CO)(CD₃CN)I₃]

Cas No:163079-13-8

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