1,2-O-Isopropylidenefuranose Templates for the Synthesis of Complex Cyclic Ethers via Neighboring Group Participation by the Acetal Ring Oxygen

DOI: 10.1021/jo00105a012

Source and publish data:

Journal of Organic Chemistry p. 7986 - 7993 (1994)

Update date:2022-08-05

Topics:

Authors:

Shan, Weifang

Wilson, Phyllis

Liang, Wei

Mootoo, David R.

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Article abstract of DOI:10.1021/jo00105a012

Novel strategies are described for the direct transformation of C5-allylated-1,2-O-isopropylidene-furanoses into complex cyclic ethers.Reaction of these substrates with iodonium ion under aqueous conditions resulted in the facile formation of 2,5-disubsti

Full text of DOI:10.1021/jo00105a012

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