The stereoselective derivatisation of the Re or Si faces of the Δ9,10-double bond of soraphen A

DOI: 10.1016/0040-4020(95)00089-Q

Source and publish data:

Tetrahedron p. 3159 - 3174 (1995)

Update date:2022-08-06

Topics:

Authors:

Hofle Hofle

O'Sullivan

Rihs Rihs

Sutter Sutter

Winkler Winkler

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Article abstract of DOI:10.1016/0040-4020(95)00089-Q

The Δ^9,10 double bond of soraphen A was found to react selectively on the Si face, whereas the same double bond in the hydroxy-ketone tautomer of soraphen A is attacked on the Re face. It became possible to prepare products of chosen stereochem

Full text of DOI:10.1016/0040-4020(95)00089-Q

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Product name:5,7-bis-O-trimethylsilyl-soraphen A

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