Russian Chemical Bulletin p. 660 - 665 (1994)
Update date:2022-08-06
Topics:
Pasechnik, M. P.
Aladzeva, I. M.
Matrosov, E. I.
Pisarevskii, A. P.
Struchkov, Yu. T.
et al.
The crystalline complex A) was isolated by the interaction of (N,N-diethylcarbamoylmethyl)diphenylphosphine sulfide Ph2P(S)CH2C(O)NEt2 (L1) with AgNO3 in different solvents as the ratios of metal-ligand = 1:1 and 1:2.According to the X-ray data, complex A is a center-symmetric dimer with bridge sulfur atoms.The cations of the metal are in a tetrahedral environment formed by two S atoms and the O atoms of CO and NO3 groups.The interaction of L1 with AgNO3 was studied in solution by IR spectroscopy, and the structures of the complexes formed are discussed. - Key words: silver complexes, organothiophosphorus compounds, vibrational spectra, X-ray analysis.
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Doi:10.1016/S0040-4039(00)76987-5
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