Journal of Organic Chemistry p. 3600 - 3611 (1995)
Update date:2022-07-30
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White
Cammack
Sakuma
Rewcastle
Widener
D-(-)-Quinic acid (1) was converted to the fungal metabolites mycosporin I (2) and mycosporin-gly (13) via the iminophosphorane 64. The latter was prepared in 10 steps from 1 using oxidative bromination of quinide 33 to furnish 41. Reduction of the γ-lact
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Doi:10.1107/S010827019400898X
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