Aromatic phosphonate-phosphines

Article abstract of DOI:10.1080/10426509608038791

Aromatic phosphonate-phosphines 3a,b are obtained by reaction of 4-halogen-substituted phenylphosphonates 2a.b.c and lithuim piphenylphosphide. They can be transformed into air-stable phosphine-boranes 4a,b by co-ordination of the borane-THF complex. The reaction of the phosphonate-phosphine 3b wth [ClRh(cod)]. affords the coresponding rhodium phosphine complex 5. The cyclic phosphinate 8 with a bunaphthalene skeleton can be obtained by a new cyclisation reaction of 2-bromo-2′-diisopropylphospono-binaphthalene 7 with lithium diphenylphosphide.

Full text of DOI:10.1080/10426509608038791

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Phosphorus, Sulfur, and Silicon and
the Related Elements
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AROMATIC PHOSPHONATE-
PHOSPHINES
Angela Köckritz a , Axel Weigt a & Michael Kant a
a Institut für Angewandte Chemie Berlin-Adlershof , Rudower
Chaussee 5, 12489, Berlin, Bundesrepublik Deutschland
Published online: 24 Sep 2006.
To cite this article: Angela Köckritz , Axel Weigt & Michael Kant (1996) AROMATIC
PHOSPHONATE-PHOSPHINES, Phosphorus, Sulfur, and Silicon and the Related Elements, 117:1,
287-292, DOI: 10.1080/10426509608038791
To link to this article: http://dx.doi.org/10.1080/10426509608038791
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