Tetrahedron p. 6273 - 6284 (1995)
Update date:2022-08-05
Topics:
Enders, Dieter
Jandeleit, Bernd
Prokopenko, Oleg F.
The highly convergent synthesis of (R,R)-6,12-dimethylpentadecan-2-one <(R,R)-1>, the bioactive form of the sex pheromone produced by female adults of the banded cucumber beetle Diabrotica balteata LeConte, in high enantio- and diastereomeric purity (ee >/= 99percent, de >/= 98percent) and good overall yield (13 steps, 39percent) is described.The stereogenic centres were generated by nucleophilic addition of allyltrimethylsilane to an enantiopure planar chiral (?-allyl)-tetracarbonyliron(1+)-complex.
View MoreTianjin Te-An Chemtech Co., Ltd.(expird)
Contact:+86-22-65378638
Address:A5-8, No.80 Haiyun Street, TEDA
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)
Contact:22-58516360
Address:tianjin
Jinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
website:https://www.yurisolar.com/en
Contact:+86-29-81101199
Address:No. 560, East Hangtian Road, Xi'an, China
shandong zhongke taidou chemical co.,ltd
Contact:86-531-88682301
Address:Jinan shandong Province CHina
Doi:10.1002/anie.200800815
(2008)Doi:10.1016/S0022-328X(00)80048-0
(1963)Doi:10.1021/ol801332n
(2008)Doi:10.1039/b603002e
(2006)Doi:10.1080/15421406.2010.497115
(2010)Doi:10.1016/S0040-4039(01)80345-2
(1989)