Tetrahedron p. 6273 - 6284 (1995)
Update date:2022-08-05
Topics:
Enders, Dieter
Jandeleit, Bernd
Prokopenko, Oleg F.
The highly convergent synthesis of (R,R)-6,12-dimethylpentadecan-2-one <(R,R)-1>, the bioactive form of the sex pheromone produced by female adults of the banded cucumber beetle Diabrotica balteata LeConte, in high enantio- and diastereomeric purity (ee >/= 99percent, de >/= 98percent) and good overall yield (13 steps, 39percent) is described.The stereogenic centres were generated by nucleophilic addition of allyltrimethylsilane to an enantiopure planar chiral (?-allyl)-tetracarbonyliron(1+)-complex.
View MoreYuan Shi(SuQian)Biotechnology Co.,Ltd
website:http://www.yuanshibio.com
Contact:+86-527-84226672
Address:jiangsu suqian
Tianjin SPHINX SCIENTIFIC LAB.
Contact:+86-022-66211289
Address:Tianda high-tech Park. No.80,the 4th Avenue
Henan Yellow River New Material Technology Co.Ltd.
website:http://www.yellowriverchem.com
Contact:0086-373-7278760
Address:Chengguan Town, Yuanyang County
Contact:86-371-63655023
Address:No.85,jinshui road,zhengzhou,China
Contact:+86-021-6989-5597
Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
Doi:10.1002/anie.200800815
(2008)Doi:10.1016/S0022-328X(00)80048-0
(1963)Doi:10.1021/ol801332n
(2008)Doi:10.1039/b603002e
(2006)Doi:10.1080/15421406.2010.497115
(2010)Doi:10.1016/S0040-4039(01)80345-2
(1989)