mer,cis-Chlorotris(dimethylphenylphosphine)nitrido(trifluoromethylsulfonato)rhenium(V)

DOI: 10.1107/S0108270195000692

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1250 - 1251 (1995)

Update date:2022-08-03

Topics:

Authors:

Abram, Ulrich

Walker, Isabell

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Article abstract of DOI:10.1107/S0108270195000692

The title compound, , is formed by the reaction of with excess trifluoromethanesulfonic acid.The phosphine ligands are coordinated meridionally.The trifluoromethanesulfonate ligand is in a trans position with respect to the terminal nitrido N atom with an exceptionally long Re-O bond length of 2.403(5) Angstroem, which is the result of the strong structural trans influence of 'N^3-'.

Full text of DOI:10.1107/S0108270195000692

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