Synthesis and transformations of 1,3,5-triazabicyclohexanes

DOI: 10.1007/BF00698884

Source and publish data:

Russian Chemical Bulletin p. 2004 - 2009 (1993)

Update date:2022-09-26

Topics:

Authors:

Makhova,, N. N.

Mikhailyuk, A. N.

Bova, A. E.

Chabina, T. V.

Khmel'nitskii, L. I.

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Article abstract of DOI:10.1007/BF00698884

The conditions for the condensation of 1,2-nonsubstituted diaziridines with CH2O and NH3 (or AlkNH2) to the corresponding 1,3,5-triazabicyclo<3.1.0>hexanes have been found and 3-phenylsulfonyl, 3-trimethylsilyl, 3-nitroso, and 3-nitro derivatives of the latter have been obtained. - Key words: diaziridines, condensation; 1,3,5-triazabicyclo<3.1.0>hexanes, α-aminomethylation, nitrosation, denitrosation, silylation, nitration.

Full text of DOI:10.1007/BF00698884

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