Synthesis and transformations of 1,3,5-triazabicyclohexanes

Article abstract of DOI:10.1007/BF00698884

The conditions for the condensation of 1,2-nonsubstituted diaziridines with CH2O and NH3 (or AlkNH2) to the corresponding 1,3,5-triazabicyclo<3.1.0>hexanes have been found and 3-phenylsulfonyl, 3-trimethylsilyl, 3-nitroso, and 3-nitro derivatives of the latter have been obtained. - Key words: diaziridines, condensation; 1,3,5-triazabicyclo<3.1.0>hexanes, α-aminomethylation, nitrosation, denitrosation, silylation, nitration.