Di- and Tri-metallic Complexes containing Two Bridging Cyclodiphosphazane Ligands: the Crystal Structure of 2>2>

DOI: 10.1039/DT9950001933

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1933 - 1938 (1995)

Update date:2022-08-03

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Authors:

Reddy, Venkata S.

Krishnamurthy, Setharampattu S.

Nethaji, Munirathinam

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Article abstract of DOI:10.1039/DT9950001933

The reactions of the mononuclear cyclodiphosphazane complexes, cis-2>2> with (nbd = norbornadiene). or (cod = cycloocta-1,5-diene) afforded the homobimetallic complexes, 2>2> (R = C6H4Me-p 5 or CH2CF3 6) or the heterobimetallic complexes, 2>2MCl2> (R = C6H4Me-p; M = Pd 7 or Pt 8).In all the above complexes, the two metal moieties are bridged by two cyclodiphosphazane ligands.The reactions of the mononuclear complexes, cis-A)2>> with afforded the trinuclear complexes, cis-A)2>>2> (M' = Pd, M = Mo, A = P(OMe)3 10; M' = Pt, M = Mo, A = P(OMe)3 11; M' = Pd, M = W, A = NHC5H10 12; M' = Pt, M = W, A = NHC5H10 13).The structure of the complex 5 has been determined by single-crystal X-ray crystallography.

Full text of DOI:10.1039/DT9950001933

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