The chloramination of some substituted stibines

Article abstract of DOI:10.1021/ic50052a024

Trimethyl-, triethyl-, tri-n-propyl-, tri-n-butyl-, and triphenylstibines react with ammonia-free chloramine or an ammonia-chloramine mixture to produce compounds of the type [R₃Sb(Cl)]₂NH (I). These compounds readily hydrolyze to [R₃Sb-(Cl)]₂O (II ). Further reactions of II are also described. Infrared and proton magnetic resonance studies were carried out on compounds of types I and II and on a variety of other antimony compounds. Qualitative assignments of infrared bands are given.