
Inorganic Chemistry p. 1178 - 1182 (1967)
Update date:2022-08-05
Topics:
McKenney, Robert L.
Sisler, Harry H.
Trimethyl-, triethyl-, tri-n-propyl-, tri-n-butyl-, and triphenylstibines react with ammonia-free chloramine or an ammonia-chloramine mixture to produce compounds of the type [R3Sb(Cl)]2NH (I). These compounds readily hydrolyze to [R3Sb-(Cl)]2O (II ). Further reactions of II are also described. Infrared and proton magnetic resonance studies were carried out on compounds of types I and II and on a variety of other antimony compounds. Qualitative assignments of infrared bands are given.
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Doi:10.1016/j.molstruc.2016.03.008
(2016)Doi:10.1021/jo00119a020
(1995)Doi:10.1039/c1ob06209c
(2011)Doi:10.1016/S0040-4039(00)97715-3
(1990)Doi:10.1080/07328319608002438
(1996)Doi:10.1139/v67-083
(1967)