Journal of Materials Chemistry p. 1253 - 1258 (1996)
Update date:2022-08-04
Topics:
Gordon, John
Sheldon, Timothy J.
Bradley, Donal D. C.
Burn, Paul L.
We have found that by the inclusion of a conjugated spacer it is possible to synthesise a poly(1,4-phenylenevinylene) derivative with an electron-withdrawing group attached directly from the substituted monomer. We describe a route for the synthesis of an electronically asymmetric styryl-derivatised poly(1,4-phenylenevinylene). The preparation was achieved in two steps from the nitrostyryl-substituted arylenedimethylene bisbromo monomer 13. In the first step, base-induced polymerisation of 13 afforded the soluble and processible precursor polymer 14. The precursor polymer 14 could then be converted in the second step to the insoluble and unprocessible conjugated polymer 15 by thermal treatment in the solid state.
View MoreJinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Contact:027-87677569
Address:Room 2203, yujingmingmen Buidling One, xiongchu Road, wuhan city, hubei province, China
Shanghai Bocimed Pharmaceutical Co., Ltd.
website:http://www.bocimed.com
Contact:+86-21-68861632
Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Anhui Gusheng Import&Export CO.,LTD
Contact:86-551-63662296
Address:Jinzhai Road NO.162 ,hefei, china
Binzhou Holly Pharmaceutical Co.,Ltd.
Contact:74517
Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Doi:10.1021/jo960428+
(1996)Doi:10.7164/antibiotics.51.771
(1998)Doi:10.1016/S0040-4039(00)78560-1
(1994)Doi:10.1246/bcsj.59.487
(1986)Doi:10.1039/DT9950001839
(1995)Doi:10.1002/poc.1760
(2011)
