Formation of Mo, W, Fe and Ru di(metal σ-acetylide) derivatives of2.5-diethynylthiophene via palladium-catalyzed metal-carbon coupling

DOI: 10.1016/0022-328X(94)05471-M

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C13 (1995)

Update date:2022-07-30

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Authors:

Viola, Egidio

Lo Sterzo, Claudio

Crescenzi, Raffaella

Frachey, Giuseppe

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Article abstract of DOI:10.1016/0022-328X(94)05471-M

In the presence of catalytic amount of bis(acetonitrile)dichloropalladium(II) [(CH3CN)2PdCl2] the iodocyclopentadienylmetal complexes [(η(5)-C5H5)M(CO)nI] (1, M = Mo, n = 3; 2, M = W, n = 3; 3 M = Fe, n = 2; 4, M= Ru, n = 2) couple in a 2 to 1 ratio with

Full text of DOI:10.1016/0022-328X(94)05471-M

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Product name:2,5-bis[(tributylstannyl)ethynyl]thiophene

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