Oxidative addition of cationic (η6-chloroarene)tricarbonylmanganese compounds to palladium(0) complexes. Synthesis, characterisation and reactivity

DOI: 10.1016/0022-328X(95)05472-2

Source and publish data:

Journal of Organometallic Chemistry p. C22 - C24 (1995)

Update date:2022-08-03

Topics:

Authors:

Carpentier, Jean-Francois

Castanet, Yves

Brocard, Jacques

Mortreux, Andre

Rose-Munch, Francoise

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(95)05472-2

The oxidative addition of the coordinated chloroarene in <(4-RC6H4Cl)Mn(CO)3> (R=H, OCH3; X=PF6, BF4) to proceeds readily at room temperature to give <<η⁶-<(4-RC6H4)(Mn(CO)3)>. 31P<1H> NMR analysis of these square

Full text of DOI:10.1016/0022-328X(95)05472-2

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Product name:cis-[(Pd(PPh₃)2Cl)(C₆H₅)(Mn(CO)3)]PF₆

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