Synthesis of 'retro-inverso' peptide nucleic acids: 1. Characterization of the monomers

DOI: 10.1016/0040-4039(95)01374-Q

Source and publish data:

Tetrahedron Letters p. 6937 - 6940 (1995)

Update date:2022-09-26

Topics:

Authors:

Krotz, Achim H.

Buchardt, Ole

Nielsen, Peter E.

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Article abstract of DOI:10.1016/0040-4039(95)01374-Q

Novel monomeric building blocks 4a and 4b of peptide nucleic acids with an N-(aminomethyl)β-alanine backbone ('retro-inverso' PNA) are conveniently synthesized via Hofmann rearrangement. In the major rotamer the side chain carbonyl points toward the C terminus.

Full text of DOI:10.1016/0040-4039(95)01374-Q

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