Tetrahedron Letters p. 6937 - 6940 (1995)
Update date:2022-09-26
Topics:
Krotz, Achim H.
Buchardt, Ole
Nielsen, Peter E.
Novel monomeric building blocks 4a and 4b of peptide nucleic acids with an N-(aminomethyl)β-alanine backbone ('retro-inverso' PNA) are conveniently synthesized via Hofmann rearrangement. In the major rotamer the side chain carbonyl points toward the C terminus.
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