Reaction of aminocarbene complexes of chromium and tungsten 6. Rearrangements of and insertions of alkynes into aziridinylcarbene complexes

DOI: 10.1016/0022-328X(94)05355-F

Source and publish data:

Journal of Organometallic Chemistry p. 43 - 52 (1995)

Update date:2022-08-05

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Authors:

Denise, Bernard

Parlier, Andree

Rudler, Henri

Vaissermann, Jacqueline

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Article abstract of DOI:10.1016/0022-328X(94)05355-F

Pentacarbonyl<(2-methylaziridinyl)(methyl)carbene>chromium(0) (2a) reacts with LiBu followed by H2O to regenerate the starting carbene complex.Treatment of the same reaction mixture with D2O leads to the perdeuteromethyl carbene complex 2D3.However, addit

Full text of DOI:10.1016/0022-328X(94)05355-F

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