Synthesis p. 44 - 46 (1995)
Update date:2022-08-06
Topics:
Baumann
Buchholz
Stamm
The carbanions of Horner reagents (α-cyanated and α-acylated phosphonic esters 2, 8 and 11) are amidoethylated with activated aziridines 1a-e. Twofold amidoethylations is observed with the phosphononitrile 2 only. The primary products 9 formed the phosphono acetate 8 tend to cyclize yielding phosphonopyrrolidinones 10.
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Doi:10.1021/jo01272a075
(1968)Doi:10.1021/om00009a010
(1995)Doi:10.1021/ic00125a036
(1995)Doi:10.1021/jm00065a012
(1993)Doi:10.1039/c9md00050j
(2019)Doi:10.1080/00945719708003157
(1997)
