Bifunctional phosphines as ligands and as substrates: Synthesis of iridium hydrido, carbonyl, alkynyl, vinyl, and vinylidene complexes from i-Pr2PCH2CH2X (X = OMe, NMe2), including the X-ray crystal structure of

Article abstract of DOI:10.1021/om00008a013

Treatment of [IrCl(C₈H₁₄)₂]₂ (5) with 1-Pr₂PCH₂CH₂OMe (6) leads to the formation of the octahedral hydridoiridium(III) complex [IrHCl{κ²(C,P)-CH₂OCH₂