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Stereoselective free radical cycloaddition-macrocyclization in facile synthesis of trans-cyclohexano-fused 12-membered crown thioethers

DOI: 10.1016/0040-4020(95)00707-F

Source and publish data:

Tetrahedron p. 11431 - 11444 (1995)

Update date:2022-08-03

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Authors:

Troyansky, Emmanuil I.Troyansky, Emmanuil I.

Ismagilov, Rustem F.Ismagilov, Rustem F.

Samoshin, Vyacheslav V.Samoshin, Vyacheslav V.

Strelenko, Yury A.Strelenko, Yury A.

Demchuk, Dmitry V.Demchuk, Dmitry V.

Nikishin, Gennady I.Nikishin, Gennady I.

Lindeman, Sergey V.Lindeman, Sergey V.

Khrustalyov, Viktor N.Khrustalyov, Viktor N.

Struchkov, Yury T.Struchkov, Yury T.

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Article abstract of DOI:10.1016/0040-4020(95)00707-F

Homolytic cycloaddition of dithiols 1,2 derived from trans- and cis-1,2-cyclohexanediols to alkynes, induced by Pr3B-O2, offers an extremely simple approach to trans- and cis-cyclohexano-fused 12-membered crown thialactones 4a-c-7a-c

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Full text of DOI:10.1016/0040-4020(95)00707-F

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Product name:cis-1,2-bis(mercaptoacetoxy)cyclohexane

Cas No:168106-37-4

168106-37-4

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