Kinetics of intramolecular additions of the aminyl radicals to carbonyl groups and subsequent ring opening

DOI: 10.1016/0040-4020(95)00459-L

Source and publish data:

Tetrahedron p. 8437 - 8446 (1995)

Update date:2022-08-05

Topics:

Authors:

Kim, Sunggak

Yoon, Kwang Sub

Kim, Sung Soo

Seo, Hyo Seok

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)00459-L

The rates of cyclizations of the aminyl radicals were measured (2a: k₁ = 5.1 × 10⁵ s^-1, 2b: k₁ = 3.1 × 10⁴ s^-1). The angle strains slow down the ring closures. The cyclized oxy radicals 3a

Full text of DOI:10.1016/0040-4020(95)00459-L

Products guided by the article

Product name:ethyl 2-(2-phenylethyl) crotonate

Cas No:168912-16-1

R&D Labs maybe for 168912-16-1

Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China

Relevant to this article

Electrochemical synthesis and crystal structure of silver(I) complexes with some heterocyclic thiones

Doi:10.1039/DT9960002047
(1996)
Radioiodination of Aryl-alkyl cyclic sulfates

Doi:10.3390/molecules171113266
(2012)
A route to homochiral (S)-O-methyl mandelic acid and related α-alkoxy carboxylic acids from isopropylidene glycerol

Doi:10.1080/00397919508011831
(1995)
Chiral diselenides in the total synthesis of (+)-samin

Doi:10.1021/jo952093m
(1996)
A simple approach to 1',1'-a-methano carbocyclic thymidine

Doi:10.1039/c39950001345
(1995)
Generation of allenic samarium complexes from propargylic ethers and (C₅Me₅)₂Sm(thf)₂, and their electrophilic trapping

Doi:10.1016/0040-4039(95)01260-O
(1995)

Article Doi