Optically Active Bicyclooctane Derivatives; Synthesis of (1S,4R,6R)-6-Hydroxybicyclooctan-2-one from Its Enantiomer

DOI: 10.1016/0957-4166(95)00105-X

Source and publish data:

Tetrahedron Asymmetry p. 957 - 960 (1995)

Update date:2022-08-04

Topics:

Authors:

Almqvist, Fredrik

Frejd, Torbjoern

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Article abstract of DOI:10.1016/0957-4166(95)00105-X

(1S,4R,6R)-6-Hydroxybicyclo<2.2.2>octan-2-one, (+)-1, is synthesized from its enantiomer in 6 steps using a combination of orthogonal protecting groups and red-ox chemistry.

Full text of DOI:10.1016/0957-4166(95)00105-X

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Product name:(1R,2R,4S,6S)-2-(t-butyldiphenylsilyloxy)-6-(2-tetrahydropyranyloxy)-bicyclo<2.2.2>octane

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