Crystal and molecular structure of diphenylthallium(III) tetraphenyldithioimidodiphosphinate, [TlPh2{(SPPh2)2N}], containing a new inorganic (carbon-free) TlS2P2N metallocycle

Article abstract of DOI:10.1016/0277-5387(94)00296-Q

Reacting potassium tetraphenyldithioimidodiphosphinate (KL) with diphenylthallium(III) bromide in methanol yielded the compound [TlPh2(L)], the structure of which was determined by X-ray diffraction. The unit cell contains two independent molecules with s