Stabilization and reaction behaviour of a terminal phosphido unit on a monomolecular Pt(II) centre. Synthesis and X-ray structure of a cationicdiphenylphosphine complexes [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(I

DOI: 10.1016/0020-1693(95)90074-G

Source and publish data:

Inorganica Chimica Acta p. 327 - 338 (1995)

Update date:2022-09-26

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Authors:

Maassarani, Fida

Davidson, Michael F.

Wehman-Ooyevaar, Ingrid C. M.

Grove, David M.

Koten, Martijn A. van

et al. et al.

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Article abstract of DOI:10.1016/0020-1693(95)90074-G

Reaction of diphenylphosphine with the complexes [Pt(NCN)(H2O)]X (NCN=C6H3(CH2NMe2)2-2,6; X=BF4 (1a), OSO2CF3 (1b)) leads to substitution of the H2O ligand to afford the ionic Pt(II) complexes [Pt(NCN)(PHPh2)]X (X=BF4 (2a), OSO2CF3 (2b)). The X-ray struct

Full text of DOI:10.1016/0020-1693(95)90074-G

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Product name:[Pt(C₆H₃(CH₂N(CH₃)2)2)(PH(C₆H₅)2)]⁽¹⁺⁾*OSO₂CF₃^(1-)=[Pt(C₆H₃(CH₂N(CH₃)2)2)(PH(C₆H₅)2)](OSO₂CF₃)

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