Study of Mechanism of Reduction of 2-Bromo-1-(p-X-phenyl)ethylidenemalonitrile by 1-Benzyl-1,4-dihydronicotinamide and 10-Methyl-9,10-dihydroacridine

DOI: 10.1016/0040-4020(95)00559-Q

Source and publish data:

Tetrahedron p. 9671 - 9680 (1995)

Update date:2022-08-05

Topics: Protonation Nucleophilic addition Elimination

Authors:

Liu, You-Cheng

Li, Bin Li, Bin

Guo, Qing-Xiang

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Article abstract of DOI:10.1016/0040-4020(95)00559-Q

The reduction of 2-bromo-1-(p-X-phenyl)ethylidenemalonitrile (X-BPM: X=H, F, Cl, Br, CN) by NADH models BNAH and AcrH2 has been investigated.Based on product analysis, kinetic isotope effect, and free energy relationship, a direct hydride transfer and an

Full text of DOI:10.1016/0040-4020(95)00559-Q

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