Tetrakis (perfluoropropyl)tin and other perfluoropropyltin compounds: synthesis, characterization and reactivity

DOI: 10.1016/0022-328X(95)00332-K

Source and publish data:

Journal of Organometallic Chemistry p. 131 - 136 (1995)

Update date:2022-07-29

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Authors:

Seyferth, Dietmar

Richter, Frank

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Article abstract of DOI:10.1016/0022-328X(95)00332-K

The n-perfluoropropyltin compounds (C3F7)4 Sn, (C3F7)3SnCH3, (C3F7)2SnR2 (R = CH3 and CH=CH2), (C3 F7)2(R)SnCl (R = CH3 and CH=CH2) and C3F7(C6H5)2SnCl were prepared by the reaction of C3F7MgX (X = CI or Br) with the appropriate organotin halide.A novel 1:1 adduct was formed between (C3F7)4Sn and 1,10-phenanthroline.Bromine cleavage of (C3F7)2Sn(CH=CH2)2 gave (C3F7)2SnBr2. (C3F7)4Sn was found to be remarkably stable toward cleavage by Br2, HCl and SnCl4.Keywords: Tin; Fluorocarbons

Full text of DOI:10.1016/0022-328X(95)00332-K

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